Abstract

We derive a rigorous {ital a} {ital posteriori} bound on the error in energy eigenvalues obtained using {ital C}{sup 1} finite elements, as well as several {ital a} {ital posteriori} error estimates, and test them numerically with potentials of analytically-known eigenspectrum. We also obtain numerical solutions, with error bounds and estimates, for the octic oscillator potential, illustrating the ability of the finite-element method to resolve-nearly degenerate states with extremely narrow splitting. The incorporation of adaptive refinement is shown to reduce the number of degrees of freedom needed to achieve a given level of accuracy.

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