Erosion-corrosion behaviour of high manganese steel used in slurry pipelines

Abstract

The regular replacement and maintenance of steel pipes used to transport slurry in oil sands mining and extraction continue to represent a major expense for oil sands operations. Pipeline steels such as API 5 L X65 and X70 are the main materials for the slurry transport system. In our previous work, dual-phase stainless steel showed excellent performance in aeriated (high dissolved oxygen) slurries operated at low to moderate velocities involving erosion-corrosion. However, the benefits of using stainless steel diminish as the oxygen in slurry is depleted or at higher slurry velocities at which mechanical properties, particularly deformation energy or strain-hardening capability, of the steel become more dominant. This article reports our recent studies on erosion-corrosion of high manganese steel at different slurry velocities (3.5 m/s and 5.5 m/s) and different dissolved oxygen levels (0.6 ppm and 3.8 ppm). The erosion-corrosion tests were performed at 60 °C in sand-containing slurry (20% vol. silica) with 500 ppm chloride, which simulated common field situation. Characterization of the steel was carried out with optical and scanning electron microscopy, energy dispersive x-ray spectrometry, x-ray diffraction technique, micro-mechanical probe, and electrochemical testing. The performance of the high manganese steel was compared to those of API 5 L pipeline steels commonly used in slurry transport, ASTM A1053 Gr.50 dual-phase ferritic-martensitic stainless steel, and AR400 martensitic hard plate. Results of this investigation demonstrate how the high strain-hardening capability of the high manganese steel produces an outstanding erosion resistance, which is more than two times as high as those of ferritic steels. The results are compared to those obtained through field trials performed in an oil sands coarse tailings pipeline.