Equilibrium vapor pressure properties for absorbent and adsorbent materials

Abstract

• Vapor pressure correlations compiled for 38 refrigerants and 262 working pairs. • Refrigerants include water, ammonia, CO 2 , alcohols, HFCs, HFOs, and hydrocarbons. • Generalized vapor pressure functional forms enable cross comparisons. • Correlation valid ranges are provided where available. • An enabling dataset for thermodynamic simulations of sorption systems. Sorption devices are important tools for the efficient utilization of fuels and waste heat. Amid a tremendous diversity of cycles and applications, all sorption systems have an equilibrium vapor pressure that depends on the sorbent temperature and composition. The vapor pressure properties of working fluids are reported in the literature in a variety of ways, which impedes wide-ranging cross comparisons or screening studies for novel applications. This work compiles equilibrium vapor pressure properties for 123 liquid absorbents with 31 absorbates and 139 solid adsorbents with 16 adsorbates. The adsorption pairs are represented with six functional forms. Most of the absorption pairs are represented with 10 functional forms, plus several that are represented with custom empirical equations. Because the functional forms used in the literature vary widely, in this work each functional form was generalized. This paper is designed to facilitate comparisons of working fluid properties for screening studies, provide a quick reference to existing research, and present a framework for standardizing the reportage of vapor pressure equilibrium data for existing and future working pairs.