Abstract
Catechol and TIRON bridge two cobalt centers in the cavity of the macrocyclic dicobalt dioxygen complex, forming five species in each case. In addition to the doubly bridged μ-peroxo, μ-catecholate (or TIRON) complex, mono- and diprotonated forms, as well as monohydroxo and dihydroxo species, have been detected. Under anaerobic conditions catecholate and 3,5-disulfocatecholate anions also bridge the two cobalt(II) centers, stabilizing the binuclear array
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