Abstract

The microwave spectra of the SO 2 molecule were measured in the first excited states of all the normal vibrations as well as in the second excited state of the ν 2 vibration. The quadratic force constants are calculated from the inertia defects in the excited vibrational states, and the cubic and quartic constants are determined through the changes of the rotational constants by the excitation of the vibrations, combined with the anharmonicity constants of the vibrational frequencies, x ij 's, reported by Nielsen et al. The r e structure was determined definitely and compared with various structures such as r z , r s , and r o

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