Equilibrium contact angles and dewetting in capillaries

Abstract

In this work, we extend the model of contact angles that we have previously developed for sessile drops on a wetted surface to the case of a meniscus in a capillary. The underlying physics of our model describe the intermolecular forces between the fluid and the surface of the capillary that result in the formation of a thin, non-removable fluid layer that coats the capillary wall. We describe the shape of the meniscus using a Young–Laplace equation and an incompressible, two-phase, computational fluid dynamics (CFD) calculation, both modified to take into account intermolecular forces using the disjoining pressure model. We find that our numerical solutions of the Young–Laplace equation and equilibrium meniscus shapes obtained by CFD agree well with each other. Furthermore, for capillaries that are sufficiently larger than the thickness of the non-removable film, our numerical solutions agree well with the effective contact angle model that we previously developed for sessile drops. Finally, we observe that it is possible to tune the disjoining pressure model parameters so that the intermolecular forces between the liquid and solid molecules become so strong compared to the surface tension that our formula for effective contact angle gives an imaginary solution. We analyze this situation using CFD and find that it corresponds to dewetting, where the bulk liquid detaches from the walls of the capillary leaving behind the non-removable thin liquid film.