Abstract
The equilibrium constant K2 for the dissociation of the 1-hydroxycyclohexylperoxyl radical to cyclohexanone and the hydroperoxyl radical was determined by the selective inhibition method using nitrobenzene. For cyclohexanol oxidation initiated by cumyl peroxide, (1.6 ± 0.2) × 10−4 mol/L (373 K, ortho-dichlorobenzene).
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