Abstract
If a MeIver-type trapped ion cyclotron resonance (ICR) cell is used without a quenching pulse, a steady-state abundance of ions is achieved, based on a balance between production and coIlisional ion loss to the walls. The intensity of mass signals in this unquenched mode is shown to be related to the kinetic and equilibrium parameters involved, although not in a linear fashion. Double resonance signals have meaning in certain cases. All transient intermediates and many slowly formed products are observed when using this mode.
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