Abstract

Based on the computer simulations of others of square-well mixtures, a predictive model for the coordination numbers has been proposed. This model and its modification have been extensively tested, and compared with the low density, Lee-Sandler and Lee-Chao models in terms of the Monte Carlo simulation data. For its simplicity and reasonable accuracy, the model can be used to predict the properties of square-well fluids and to develop equations of state that will be discussed in a subsequent paper.

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