Abstract
Equations of state (for example, the ideal gas equation) contain three (or more) variables and should therefore be graphically represented by three (or more!)-dimensional diagrams. Three-dimensional diagrams and models are quite common for single-phase systems, but multiphase systems are usually displayed in projection or simply sketched. Here, we present a three-dimensional phase diagram based on authentic experimental data for a unary system, carbon dioxide, with its solid, liquid and vapor phases. Such an authentic diagram appears not to have been presented before, and may improve the understanding of phase relationships.
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