Abstract
To obtain the equation of state of liquid bismuth and its melting curve, ultrasonic velocity measurements were performed in a multi-anvil apparatus. Using a series of thermodynamic relationships, we extract the volume of liquid bismuth as functions of pressure and temperature up to 973K and 4.3GPa. We also introduce a calculation process to build the thermal equations of state of each phase of solid bismuth based on their phase transition boundaries. Combining the thermodynamic parameters of liquid and solid bismuth, we employ the Gibbs equation and the Clausius-Clapeyron equation and finally derive the melting curve up to 8GPa, which shows excellent consistency with most previous theoretical and experimental results. These results not only demonstrate the accuracy of our experimental and theoretical methods, but also demonstrate the feasibility of the thermodynamic method for obtaining unknown melting curves.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
