Abstract

The spherical lattice gas is a modification of the ordinary lattice gas in which the occupation number of each cell is permitted to be any real number rather than \ifmmode\pm\else\textpm\fi{}1. However, the sum of squares of the occupation numbers is required to equal the number of cells. This permits one to evaluate the partition function by integrating over the surface of a certain sphere rather than by summing over lattice points on that surface. The partition function and the equation of state of the gas are evaluated in this way. It is found that in three dimensions the gas condenses, but not in one or two dimensions. Graphs of the phase transition curve and of the isotherms in three, two, and one dimension are presented.The analytical work is simplified by taking advantage of the relationship between the properties of the lattice gas and of the Ising model of a ferromagnet. This relationship, demonstrated by C. N. Yang and T. D. Lee for the ordinary lattice gas and Ising model, also applies to the spherical lattice gas and the spherical model of a ferromagnet. The properties of the latter have been evaluated by T. H. Berlin and M. Kac. Graphs of the isotherms of the spherical model of the magnet, which were found in the course of the work, are also presented.

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