Abstract

As an extension of earlier EPR studies of the radicals formed from acyclic olefinic substrates with the use of the TiC1 3H 2O 2 radical-generating method, results are presented of an analogous TiC1 3H 2O 2-based investigation carried out over the temperature range 10–40°C with the use of cyclic unsaturated substrates in acidified aqueous solution, namely, Δ 2-dihydrofuran, Δ 2-dihydropyran, 2-methylfuran, 2-acetylfuran, and furfurylamine. The EPR spectra of six radicals produced from these cyclic substrates are reported.

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