Abstract
Abstract Electron paramagnetic resonance (EPR) spectra of Mn2+ and Cu2+ ions in some Mn+- and Cu+-implanted multicomponent silicate (20Na2O10B2O370SiO2, mol%) and phosphate (36P2O544Na2O20Al2O3 and 65P2O510B2O310Al2O315MgO, mol%) glasses are presented. About 10% of the implanted copper is present as Cu2+ ions surrounded by six ligands which form a tetragonally elongated octahedron. The concentration of Mn2+ ions in the implanted layers of some glasses is comparable with that of implanted manganese ions. The EPR spectra of Mn+-implanted high-phosphate glass indicate that Mn2+ ions can exist in the implantation layers in local environments similar to those present in bulk glasses with appropriate composition. In addition, Mn2+ ions are present in the implantation layers as paramagnetic ions coupled by spin-spin interactions or antiferromagnetic MnO crystals.
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