Abstract
The EPR spectra of glassy solutions in tetrachloroethane containing equimolar amounts of two metalloporphyrins were measured at 77 K. The metalloporphyrins are CuP, AgP and VOP, where P is mesoporphyrinIX dimethyl ester. The spectra show evidence of heterodimer formation: in the case of CuPAgP the EPR spectrum of the heterodimer was obtained through computer manipulation and the EPR parameters determined. The spectra of CuPVOP and AgPVOP are consistent with the presence of two heterodimeric species.
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