EPR and NMR spectroscopic studies of [MoL2(MeC identical to CMe)Cp]z (L = P-donor ligand, z = 0 and 1): fluxionality in a metal-alkyne redox pair.

Christopher J. Adams,Philip H. Rieger,Neil G. Connelly

doi:10.1039/b108561c

EPR and NMR spectroscopic studies of [MoL2(MeC identical to CMe)Cp]z (L = P-donor ligand, z = 0 and 1): fluxionality in a metal-alkyne redox pair.

Christopher J. Adams, Philip H. Rieger + Show 1 more

https://doi.org/10.1039/b108561c

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Journal: Chemical communications (Cambridge, England)	Publication Date: Nov 13, 2001
Citations: 10

Affiliation: University of Bristol, Brown University

#EPR Spectroscopic Studies #MeC CMe + Show 8 more

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Abstract

Variable temperature NMR and EPR spectroscopic studies provide rates and activation parameters for alkyne rotation and oscillation, respectively, in the fluxional redox pair [Mo(P(OMe)3)2(MeC identical to CMe)Cp][BF4] (diamagnetic) and [Mo(P(OMe)3)2(MeC identical to CMe)Cp] (paramagnetic).

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