Epoxy systems with improved water resistance, and the non‐fickian behaviour of epoxy systems during water ageing

Abstract

AbstractN,N‐Bis (2, 3‐epoxypropyl) aniline and 4,4′‐methylenebis‐[N,N‐bis (2,3‐epoxypropyl) aniline] containing bromo, chloro, trifluoromethyl or polyfluoroalkoxy substituents were synthesised and cured with aromatic diamines in order to investigate the effect of substituted halogen on water absorption. Significant improvements were achieved: thus use of 4,4′‐methylenebis‐[N, N‐bis (2, 3‐epoxypropyl)‐3, 5‐dichloroaniline] and 4,4′‐methylenebis‐[N,N‐bis (2,3‐epoxypropyl)‐3‐(trifluoromethyl) aniline] instead of 4,4′‐methylenebis‐[N,N‐bis (2,3‐epoxypropyl) aniline] reduced the water absorption by about a half. Departures from Fickian behaviour were observed during water immersion ageing at room temperature and were a general feature of the epoxy systems examined. Plots of water absorption against the Fickian parameter (√t/d) usually showed at least mild sigmoid character and were not independent of specimen thickness. Further, slow continued uptake of water occurred during long‐term ageing, and evidence is provided that the associated network distortions are reversible.