Abstract

We report morphology, thermal analysis and beam diffraction of polyethylene chlorine-substituted precisely on every 21st backbone carbon, after solution crystallization induced by low-dimensional carbonaceous nanofillers (carbon nanotube and graphene). Kebab-like and rod-like nanofiller-induced crystals were separately observed on the surfaces of carbon nanotube and graphene. Fast-scan differential scanning calorimetry revealed that while the melting point of crystals grown on carbon nanotube remains close to that in the bulk phase, the melting point of crystals grown on graphene is 75 °C higher. X-ray diffraction and selected area electron diffraction suggested that graphene induces the formation of orthorhombic form, which is of higher density than the triclinic form in the bulk.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.