Abstract

A new type of thermoplastic elastomer (TPE) based on EPDM ionomer as an elastomer and polyamide-6 as a reinforcing crystalline polymer was prepared and the thermal properties of TPEs were investigated. Especially effects of neutralization of maleated EPDM (MA-EPDM) to prepare EPDM ionomer with zinc oxide and the content of polyamide-6 on the thermal properties of the blends were investigated. Both the neutralization and blending were carried out employing a twin screw extruder. It was found that the neutralization of MA-EPDM results in the increase of cooling crystallization temperatures. Polyamide-6 plays the role of reinforcing filler in the blends due to the high crystallinity. Fine dispesion of polyamide-6 in the blends was confirmed and attributed to the imide formation between the maleic anhydride of MA-EPDM and amine group of polyamide-6. TPEs based on EPDM ionomer/Polyamide-6 blends showed balanced mechanical properties with improvement in heat resistance.

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