Abstract
The major biosynthetic route to amorphigenin in Amorpha fruticosa is from rot-2′-enonic acid via cyclisation to rotenone with the (E)-methyl of the former becoming the methylene of the latter, followed by positionally non-specific hydroxylation; a subsidiary route involves positionally non-specific hydroxylation of rot-2′-enonic acid followed by chemospecific (for the methyl group) cyclisation to amorphigenin.
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