Abstract
AbstractLipase Amano PS is a suitable biocatalyst for the highly regio‐ and enantioselective transesterification of the racemic prostaglandin building block (1S*,5R*,6R*,7R*)‐(±)‐7‐hydroxy‐6‐hydroxymethyl‐2‐oxabicyclo[3.3.0]octan‐3‐one (rac‐1) yielding (1S,5R,6R,7R)‐(−)‐6‐acetoxymethyl‐7‐hydroxy‐2‐oxabicyclo[3.3.0]octan‐3‐one (2) and the unreacted (1R,5S,6S,7S)‐(+)‐enantiomer ent‐1.
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