Abstract
The stereoselective xylosylation of ( RS)-1-phenylalkyl β- d-glucosides was investigated using plant xylosyltransferase isolated from cultured Catharanthus roseus cells. Enzymatic xylosylation of ( RS)-1-phenylethyl β- d-glucoside afforded ( R)-1-phenylethyl β-primeveroside and ( S)-1-phenylethyl β- d-glucoside. The ( R)-selective xylosylation of ( RS)-1-phenylbutyl β- d-glucoside also occurred to give ( R)-1-phenylbutyl β-primeveroside and recovered ( S)-1-phenylbutyl β- d-glucoside.
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