Abstract
In this research paper, for the first time laccase from Trametes Versicolor was used as a electron-transfer biocatalyst for the aerobic regeneration of DDQ as a high reduction potential organic oxidant. Laccase/DDQ as a new bioinspired quinone-based cooperative catalytic system was used for the aerobic oxidation of sulfides and oxidative coupling of thiols with high yields at room temperature. The herein presented method is more eco-friendly and practical than other currently available methods as it is free from any toxic transition metals or halides and provides quantitative conversion under mild reaction conditions.
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