Environmental and techno-economic considerations on biodiesel production from waste frying oil in São Paulo city

- One of the obstacles in the way of wide scale industrial application of biosurfactants is the high production cost coupled with a low production rate. In order to lower the production cost surfactin production by Bacillus subtilis MTCC 2423 was studied in submerged batch cultivation using waste frying oils. It was observed that the decrease in surface tension was 56.32%, 48.5% and 46.1% with glucose, waste frying sunflower oil and waste frying rice bran oil, respectively. Biomass formation was 4.36 g/L, 3.67 g/L and 4.67 g/L for glucose, waste frying sunflower oil and waste frying rice bran oil, respectively. Product yield (g product/g substrate) was 2.1%, 1.49% and 1.1% with glucose, waste frying sunflower oil and waste frying rice bran oil as substrates. This process facilitates safe disposal of waste frying oil, as well reducing the production cost of surfactin. Keywords : Biosurfactants; Bacillus subtilis ; Surface Tension; Waste frying oils; Secondary metabolite.

The data presented in this article are related to the research article “Environmental and techno-economic considerations on biodiesel production from waste frying oil in São Paulo city” (Silva Filho et al., 2018) [1]. This article presents the variation of the concentration of waste frying oil (WFO) with the reaction time and temperature during the transesterification of WTOs collected in the residences and restaurants of the city of São Paulo. Then, the biodiesel samples were mixed with the S-10 diesel oil in order to obtain the B10, B20, B30, B40, B50, B75 and B100 blends, which were tested in a diesel engine and their power, fuel consumption and gas emissions (CO, CO2 and SO2) have been measured to verify their greenhouse effect and energy efficiency.

Process Optimization for Biodiesel Production from Waste Frying Oil over Montmorillonite Clay K-30

Harmonizing the quantification of CCS GHG emission reductions through oil and natural gas industry project guidelines

Biodiesel is a highly effective fuel with the same efficiency such as diesel oil derivative only accompanied by moderate engine modifications. This type of biofuel can be obtained from renewable sources such as vegetable, animal or frying oils. In this context, waste frying oils transesterification was studied to obtain the maximum value of biodiesel. Transesterification reactions were carried out between 70 to 90 min using waste frying oils (WFOs), methanol, and sodium hydroxide as catalyst. In order to determine the best conditions for biodiesel production, a series of experiments were carried out, using catalyst percent and temperatures in a range of 0.16 to 1.84% and 40 to 90°C, respectively. The highest biodiesel production was obtained using catalyst percent, temperature and reaction time of 0.5%, 80°C and 90 min, respectively. By statistical experimental design was possible to determine a mathematical model to predict the best operational conditions to maximize biodiesel production.

The imperative of utilising alternative fuels for the operation of internal combustion engines stems from the requirements to reduce the emissions of greenhouse gases and other contaminants, the substantial demand for fuels, and the diminishing reserves of natural resources. The global inclination towards sustainable development necessitates the employment of biofuels as a substitute for fossil fuels. Nonetheless, the expenditures on raw materials for the manufacture of biodiesel remain substantial, thus underlining the importance of exploring solutions for reducing them. An instance of this could be the utilisation of plant and animal by-products, such as used frying oils and slaughterhouse waste, as feedstock for biodiesel production. Not only will this facilitate the creation of less costly biofuel, but it will also provide an effective solution for the management of post-production waste. The objective of the research delineated in this paper was to ascertain select physicochemical attributes of second-generation biodiesel, derived from spent frying oil, as well as mixtures of this biodiesel with diesel and biodiesel concentrations of 10, 20, and 30% (v/v). The biodiesel produced is the waste frying oil methyl esters WFOME. The proprietary GW-201 reactor was employed in the production of biodiesel. For WFOME biodiesel, DF diesel, and their blends—B10, B20, and B30—properties that influence the formation process of the combustible mixture, autoignition, and combustion of fuel–air mixtures in self-ignition engines were determined. The conducted research has established that “B” type fuels prepared from WFOME and DF present a viable alternative to fossil fuels. Pure biodiesel exhibited a marginally reduced lower heating value, however, in the case of fuel mixtures comprising up to 30% (v/v) biodiesel and diesel, the lower heating values approximated that of diesel. An elevated cetane number alongside an increased flash point of pure B100 biodiesel have been noted. The values of cetane number for WFOME and DF mixtures were found to be either comparable or marginally higher than those of pure DF diesel fuel.

To improve biosurfactant production economics by the utilization of potential low-cost materials. In an attempt to utilize cost-effective carbon sources in the fermentative production of biosurfactants, various pure and waste frying oils were screened by a standard biosurfactant producing strain. Considering the regional significance, easy availability and the economical advantages, waste frying coconut oil was selected as the substrate for further studies. On isolation of more competent strains that could use waste frying coconut oil efficiently as a carbon source, six bacterial strains were isolated on cetyltrimethyl ammonium bromide-methylene blue agar plate, from a soil sample collected from the premises of a coconut oil mill. Among these, Pseudomonas aeruginosa D was selected as the potential producer of rhamnolipid. Spectrophotometric method, TLC, methylene blue active substance assay, drop collapse technique, surface tension measurement by Du Nouy ring method and emulsifying test confirmed the rhamnolipid producing ability of the selected strain and various process parameters were optimized for the production of maximum amount of biosurfactant. Rhamnolipid components purified and separated by ethyl acetate extraction, preparative silica gel column chromatography, HPLC and TLC were characterized by fast atom bombardment mass spectrometry as a mixture of dirhamnolipids and monorhamnolipids. The rhamnolipid homologues detected were Rha-Rha-C(10) -C(10) , Rha-C(12) -C(10) and Rha-C(10) -C(8) /Rha-C(8) -C(10) . These results indicated the possibility of waste frying coconut oil to be used as a very effective alternate substrate for the economic production of rhamnolipid by a newly isolated Ps.aeruginosa D. Results of this study throws light on the alternate use of already used cooking oil as high-energy source for producing a high value product like rhamnolipid. This would provide options for the food industry other than the recycling and reuse of waste frying oils in cooking and also furthering the value of oil nuts.

A novel robust CaO/ZnFe2O4 hollow magnetic microspheres heterogenous catalyst for synthesis biodiesel from waste frying sunflower oil

Serratia marcescens strain UCCM 00009 produced a mixture of gelatinase and keratinase to facilitate feather degradation but concomitant production of prodigiosin could make waste feather valorization biotechnologically more attractive. This article describes prodigiosin fermentation through co-valorization of waste feather and waste frying peanut oil by S. marcescens UCCM 00009 for anticancer, antioxidant, and esthetic applications. The stochastic conditions for waste feather degradation (WFD), modeled by multi-objective particle swarm-embedded-neural network optimization (ANN-PSO), revealed a gelatinase/keratinase ratio of 1.71 for optimal prodigiosin production and WFD. Luedeking–Piret kinetics revealed a non-exclusive, non-growth-associated prodigiosin yield of 9.66 g/L from the degradation of 88.55% waste feather within 96 h. The polyethylene glycol (PEG) 6000/Na+ citrate aqueous two-phase system-purified serratiopeptidase demonstrated gelatinolytic and keratinolytic activities that were stable for 240 h at 55 °C and pH 9.0. In vitro evaluations revealed that the prodigiosin inhibited methicillin-resistant Staphylococcus aureus at IC50 of 4.95 µg/mL, the plant-pathogen, Sclerotinia sclerotiorum, at IC50 of 2.58 µg/mL, breast carcinoma at IC50 of 0.60 µg/mL and 2,2-diphenyl-1-picryl-hydrazyl hydrate (DPPH) free-radical at IC50 of 96.63 µg/mL). The pigment also demonstrated commendable textile dyeing potential of fiber and cotton fabrics. The technology promises cost-effective prodigiosin development through sustainable waste feather-waste frying oil co-management.

Indonesia has targeted 29 % Greenhouse gas (GHG) emissions reduction in 2030 and Industry is one of the big two contributors for GHG emissions. As an industry, mining is an energy-intensive industry, and reducing energy consumption is one of the strategies to improve mining environmental performance. The aim of this paper is to estimate the GHG emission reduction in a mining project through energy reduction initiatives. A copper mine in Indonesia with processing plant capacity of 120,000 t/d and operate 111 Caterpillar 793C Haul Truck was taken as a case study. This mine site has two sources of an electricity namely coal-fired power plant with 112 MW output and diesel power plant with 45 MW output. The analysis method for calculating CO2 emission is using IPCC method where fuel consumption and emission factor are two main variables for GHG emissions. Business as usual scenario (TIER 1) showed that the average of diesel fuel consumption for fleets operation generated 294,006 t CO2-eq/y. A coal-fired power plant with average coal consumption of 350 t/d/unit generated 1.15 Mt CO2-eq/y and diesel power plant consumed 4.35 ML/y produced 11,632 t CO2-eq/y. Two energy initiative programs were identified namely fuel conversion and used oil utilisation program. The initiative scenario focused on substituting, reducing and reusing of fossil fuels including coal, diesel fuel, and used oil. This scenario was estimated to contribute the carbon emission reduction (t CO2-eq) of 258,381 annually. The involvement of mining industry in carbon emission reduction is not only helping Indonesia in achieving its GHG emissions reduction target but also increases mine site environmental performance and company image.

Waste frying oil as valueless material which is disposed to environment can be used as a promising feedstock to produce biodiesel. In this study, constructional lime was used as alkaline heterogeneous catalyst for biodiesel production from virgin and waste frying oil. After determining the best activation temperature for the catalyst (600 °C), transesterification reactions were carried out at 65 °C, MeOH to oil molar ratio of 12:1, and 1 wt% of activated constructional lime under vigorous mixing for 5 h. Yield of reactions for virgin and waste frying oil (2.17 % free fatty acid) and pretreated waste frying oil (0.918 % free fatty acid) were 87, 93.9, and 94 %, respectively. Transesterification of virgin frying oil and pretreated waste frying oil were done at 65 °C, MeOH to oil molar ratio of 6:1, and 1 wt% of KOH as catalyst under vigorous mixing for 2 h, for comparison. Yield of the reaction was 98.6 and 95.1 %, respectively. Therefore, when constructional lime is used as catalyst pretreatment of waste oil is not necessary.

Greenhouse gas (GHG) emissions reduction in the electricity sector: Implications of increasing renewable energy penetration in Ghana's electricity generation mix

The purpose of this research is to empirically reveal the effect of external technology R&D cooperation network diversity (ETRDCND) on the greenhouse gas (GHG) emission reduction and energy saving of small and medium-sized enterprises (SMEs). Besides this, this study aims at analyzing the roles of production time reduction and absorptive capacity in the relationship between SMEs’ ETRDCND and their GHG emission reduction and energy saving. GHG emission and energy usage have been playing a crucial role in aggravating global warming. Global warming results in big problems such as worldwide unusual weather and health disorders. SMEs play a substantial role in the industrial growth of the global economy, which increases GHG emission and energy consumption. By performing the ordinary least squares regression with the data of 3300 South Korean SMEs, this research reveals four points. First, ETRDCND positively influences SMEs’ GHG emission reduction and energy saving. Second, production time reduction perfectly mediates the relationship between SMEs’ ETRDCND and their GHG emission reduction and energy saving. Third, the mediating role of production time reduction in this relationship is moderated by SMEs’ absorptive capacity. Fourth, ETRDCND significantly influences SMEs’ GHG emission reduction and their energy saving only if SMEs possess their own absorptive capacity.

Conversion of waste frying palm oil into biodiesel using free lipase A from Candida antarctica as a novel catalyst

Candida antarctica lipase A was immobilized by covalent binding onto chitosan beads, and these beads were used for production of fatty acid methyl ester from waste frying canola oil. The optimum immobilization conditions were determined as enzyme concentration of 12% (v/v) and immobilization time of 24 h. Transesterification reaction was performed using enzymatic catalysis for the production of fatty acid methyl ester from waste frying oil. The results indicate that 60% yield of fatty acid methyl ester was obtained under optimum immobilization conditions. Operational stability was determined with immobilized lipase and it indicated that 74% residual activity occurred after using repeatedly for five consecutive batches of 24 h each.