Abstract

Copper slag is generated when copper and nickel ores are recovered from their parent ores using a pyrometallurgical process, and these ores usually contain other elements which include iron, cobalt, silica, and alumina. Slag is a major problem in the metallurgical industries as it is dumped into heaps which have accumulated into millions of tons over the years. Moreover, they pose a danger to the environment as they occupy vacant land (space problems). Over the past few years, studies have been conducted to investigate the copper slag-producing outlets to learn their behavior, as well as properties of slag, to have the knowledge of how to better reuse and recycle copper slag. This review article provides the environmental and socioeconomic impacts of slag, as well as a characterization of copper slag, with the aim of reusing and recycling the slag to benefit the environment and economy. Recycling methods are considered an attractive technological pathway for reducing waste and greenhouse gas emissions, as well as promoting the concept of circular economy through the utilization of waste. These metal elements have value depending on their characteristics; hence, copper slag is considered as a secondary source of valuable metals. Some of the pyrometallurgical and hydrometallurgical processes to consider are physical separation, magnetic separation, flotation, leaching, and direct reduction roasting of iron (DRI). Some of the possible metals that can be recovered from the copper slag include Cu, Fe, Ni, Co, and Ag (precious metals).

Highlights

  • Numerous slags are produced as a second stream which is not desired in various metallurgical processes, e.g., copper slag (CS) from smelting and processing of copper ore [1,2]

  • This paper focuses on copper slag which is generated by pyrometallurgical concentration of copper ores to produce copper/nickel matte by Bamangwato Concession Limited (BCL) in Botswana

  • Socioeconomic data showed that the mine environmental risk provided a risk to the ongoing socioeconomic benefits Documentary search showed that slag was disposed of efficiently while ignoring long-term environmental risks BCL data on SO2 estimates showed that 8.8% of sulfur is captured and fixed in slag and matte, 9.5% escapes via converters, and 82% leaves via the flash furnace Interviews showed that emissions from the mine have effects on breathing and being asthma, as well as the livestock’s drinking water

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Summary

Introduction

Numerous slags are produced as a second stream which is not desired in various metallurgical processes, e.g., copper slag (CS) from smelting and processing of copper ore [1,2]. The main mineral ore source for copper is chalcopyrite (CuFeS2), with the smelting process contributing approximately 80% of the global copper production from around 21 million metric tons of ores being processed in 2018. The metallurgical industries around the world are trying to find cost-effective and environmentally friendly ways to produce copper. Technologies such as microbially driven metal leaching processes are used. There are a significant number of copper processing plants around the world, and this has resulted in the production of about 24.6 million tons per year of slag, which is regarded as waste [7,8,9]. The mining sector has given much attention to this problem by focusing on research to determine how to process slag to mitigate this challenge

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