Abstract
We study the equilibrium behavior of a two-component mixture of equal-sized, nonadditive hard spheres with an interspecies collision diameter that is larger than that of each component. We calculate the thermodynamic and structural properties by simulating a system of 4000 particles in a canonical ensemble through a standard Monte Carlo technique. The phase behavior of the model is analyzed through a multiparticle correlation expansion of the statistical entropy whose prediction on the existence of a fluid−fluid separation threshold compares favorably with independent results on the phase coexistence line.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
