Abstract

Using a probabilistic model due to Kac and called by him a caricature of the dilute hard sphere gas, we compute the entropy and entropy production according to the generalized definitions proposed by the Brussels group. As the generalized ℋ-theorem describes the approach to equilibrium of the whole system, correlations play a role even if they are such that reduced distribution functions for a finite number of variables satisfy the molecular chaos condition. Nevertheless, close to equilibrium, one recovers Boltzmann's definitions. Using the results of another paper, we can give a precise meaning to what is meant by «close to equilibrium» : it is the asymptotic regime in which, to describe the evolution, one can restrict oneself to those contributions which correspond to the longest time scale in the system.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call