Abstract
Calorimetric studies show that the 14-membered macrocycle (1) incorporates copper(II) more exothermically than its less symmetric isomer (2), owing to stronger in-plane Cu–N interactions; introduction of a pyridine ring in the macrocyclic framework (3) further reduces the heat of complexation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Chemical Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
