Abstract
AbstractThe enthalpies of solution of LiI, NaI, KF, KCl, KBr, KI, RbI and CsI in anhydrous N‐methylformamide (NMF) at concentrations of about 5 × 10−3 molal have been measured with an adiabatic calorimeter. The enthalpies of dilution in NMF were calculated with the aid of the extended Debye‐Hückel theory. The differences in enthalpy of solution of the alkali iodides between (1) water and formamide and (2) water and NMF are compared with the results of van Eck's theory of ionic solvation.
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