Enthalpies of mixing of liquid systems for lead-free soldering: Cu–Sb–Sn system

Abstract

Using two different types of high temperature drop calorimeters, partial and integral enthalpies of mixing of liquid alloys were determined in the ternary Cu–Sb–Sn system. The system was investigated along four sections at 1100 K. Experimental data were used to find ternary interaction parameters by applying the Redlich–Kister–Muggianu model for substitutional solutions, and a full set of parameters describing the concentration dependence of the enthalpy of mixing was derived. From these, the isoenthalpy curves were constructed for 1100 K. The entire system shows exothermic enthalpy of mixing at the given temperature.