Abstract
The method presented previously, for calculating enthalpic second virial coefficients B 2 h from literature data on excess enthalpies of binary mixtures, is applied to alkan-1-ol/ alkan-1-ol (C 1 - C 10) mixtures. By this means 54 B 2 h values and enthalpies of solution at infinite dilution have been obtained for alkan-1-ols as solutes in other alkan-1-ols as solvents. The results for B 2 h are compared with previous results for alkanes as solutes in the same solvents. Using an empirical equation, it is possible to correlate all 54 B 2 h values for the alkan-1-ols as solutes by means of one adjustable parameter.
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