Abstract
There is one cation–anion pair in the asymmetric unit of the title compound [systematic name: 4-(3-carboxy-6-fluoro-4-oxo-1,4-dihydroquinolin-7-yl)-1-ethylpiperazin-1-ium 2,4,6-trinitrophenolate], C19H23FN3O3 +·C6H2N3O7 −. The six-membered piperazine group in the cation adopts a slightly distorted chair conformation and contains a protonated N atom. The dihedral angles between the mean planes of the cyclopropyl and piperazine rings in the cation with the 10-atom ring system of the quinolone group are 48.1 (1) and 69.9 (5)°, respectively. The picrate anion interacts with the protonated N atom of an adjacent cation through a bifurcated N—H⋯O three-center hydrogen bond, forming an R 1 2(6) ring motif. Furthermore, there is an intramolecular O—H⋯O hydrogen bond. The dihedral angle between the mean planes of the anion benzene and cation piperizine, quinoline and cyclopropyl rings are 61.3 (6), 31.1 (4) and 70.4 (9)°, respectively. The mean planes of the two o-NO2 and single p-NO2 groups in the picrate anion are twisted by 6.7 (6), 38.3 (9) and 12.8 (7)° with respect to the mean plane of the benzene ring. Strong N—H⋯O and weak intermolecular C—H⋯O hydrogen bonds in concert with weak π–π stacking interactions [centroid–centroid distances = 3.5785 (13), 3.7451 (12) and 3.6587 (13) Å] dominate the crystal packing.
Highlights
There is one cation–anion pair in the asymmetric unit of the title compound [systematic name: 4-(3-carboxy-6-fluoro4-oxo-1,4-dihydroquinolin-7-yl)-1-ethylpiperazin-1-ium 2,4,6trinitrophenolate], C19H23FN3O3+C6H2N3O7
The dihedral angles between the mean planes of the cyclopropyl and piperazine rings in the cation with the 10atom ring system of the quinolone group are 48.1 (1) and
The picrate anion interacts with the protonated N atom of an adjacent cation through a bifurcated
Summary
P. Siddarajuc a Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA, bDepartment of Chemistry, Howard University, 525 College. Street NW, Washington, DC 20059, USA, and cDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India. The dihedral angles between the mean planes of the cyclopropyl and piperazine rings in the cation with the 10atom ring system of the quinolone group are 48.1 (1) and. The picrate anion interacts with the protonated N atom of an adjacent cation through a bifurcated. N—H O three-center hydrogen bond, forming an R21(6) ring motif. The dihedral angle between the mean planes of the anion benzene and cation piperizine, quinoline and cyclopropyl rings are 61.3 (6), 31.1 (4) and 70.4 (9) , respectively. 12.8 (7) with respect to the mean plane of the benzene ring.
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