Enrichment origin of critical elements (Li and rare earth elements) and a Mo-U-Se-Re assemblage in Pennsylvanian anthracite from the Jincheng Coalfield, southeastern Qinshui Basin, northern China

Abstract

The Qinshui Basin is the largest reservoir of commercial coalbed methane in China. The No. 15 seam, one of the major coal seams for coalbed methane exploration in the Jincheng Coalfield, SE Qinshui Basin, has recently been found to be enriched in the critical element Li. This study further investigates the inorganic geochemistry of the No. 15 coal and associated rocks and reveals the enrichment origin of critical elements in these horizons. The Jincheng No. 15 coal is rich in Li, Mo, U, Se, Re, and rare earth elements and Y (REY). Concentrations of Mo, U, Se, and Re are higher in the two topmost coal benches, probably due to marine transgression in the early diagenetic stage after the peat had been established. The enrichment of Li and REY in a few lowermost coal benches is suggested to be derived from hydrothermal fluids that were related to magmatic activity (110–140 Ma) during the Yanshanian Orogeny (Late Jurassic-Early Cretaceous), or a Late Triassic-Early Jurassic abnormal thermal event occurring at 190–215 Ma. Light REY (La, Ce, Pr, and Nd) in the Jincheng No. 15 coal are predominantly associated with phosphate minerals. Heavier REY (Sm to Lu) show a mixed phosphate and organic affinity in the studied coal samples. Non-coal samples are characterized by light REY- and HREY-enrichment, which is probably inherited from the source material in the Trans North China Orogen.Trace elements in the coal can be highly enriched in the ash if the coal is combusted due to the low to medium ash yield of the coal. Critical elements, including Li, Ga, and REY, in the Jincheng No. 15 coal are considered as promising material for industrial recovery and have been previously under-estimated. On the other hand, environmentally sensitive elements including As, Hg, and Pb, while having concentrations within the normal range compared with average worldwide coals, can be highly enriched in the coal combustion residues if the coal is combusted, and thus careful consideration needs to be given to the utilisation of such coals.