Enhancing the photoelectrochemical activity and stability of plate-like WO3 photoanode in neutral electrolyte solution using optimum loading of BiVO4 layer and NiFe–LDH electrodeposition

Abstract

Tungsten trioxide (WO3) is an attractive candidate that can be used as a photoanode in the photoelectrochemical (PEC) water splitting device. However, WO3 photoanode is known for its high thermodynamic and chemical stability only in strong acidic (low pH) electrolyte solution and its relatively wide bandgap energy (2.8 eV) leads to insufficient absorption of visible light. The current study explored a WO3/BiVO4 heterojunction photoanode, consisting of plate-like WO3 covered with a uniform and highly porous BiVO4 thin layer, with electrodeposition of NiFe–LDH as a co-catalyst for oxygen evolution reaction. This top layer of BiVO4 nanostructure not only exhibited an enhancement in absorption of visible light but also protected the underneath plate-like WO3 from being attacked by the neutral environment of electrolyte solution (pH=∼7), resulting in significant improvement in its stability. The electrodeposition of NiFe–LDH using an acidic aqueous electrolyte solution (pH=3.7) was employed to overcome the sluggish kinetics of water oxidation on the surface of BiVO4. To overcome the weakness of the chemical dissolution of BiVO4 nanostructure in strong acidic solution, the electrodeposition time was carefully optimized for 50 s, leading to a uniform distribution of co-catalyst on the surface of WO3/BiVO4 heterostructure without the dissolving of BiVO4 in the acidic media. The WO3/BVO5/NiFe50 photoanode with the highest PEC performance (photocurrent density of around 1.78 mA/cm2 at 1.23 V vs. RHE) could maintain around 75% of its initial photocurrent after 24 h.