Enhancing the photocatalytic activity of TiO2 and TiO2–SiO2 by coupling with graphene–gold nanocomposites

Abstract

In the present paper, a novel composite Graphene–Gold (Gr–Au)/TiO2–SiO2 photocatalyst was synthesized and tested for the removal of methylene blue and rhodamine B in water solutions. First, Gr–Au nanoparticle composite was synthesized by simultaneous reduction and deposition of Au nanoparticles on Gr surface. The photodegradation of methylene blue and rhodamine B in aqueous solutions was studied using various photocatalysts, including neat TiO2–SiO2, Gr/TiO2–SiO2 and Gr–Au/TiO2–SiO2 composites. The Gr weight ratio in this research is 2% in the Gr/TiO2–SiO2 composites. Detailed characterization (field emission scanning electron microscope, Raman, Fourier transform infrared spectra and UV–vis absorbance spectroscopy) of such material was conducted. As a result, the uniform deposition of nanometer-sized Au NPs on the graphene sheets was observed. The Gr–Au/TiO2–SiO2 exhibited excellent photocatalytic efficiency because of the reduction of electron–hole recombination. The Gr2%–Au0.1%/TiO2–SiO2 composite had the highest photoactivity.