Abstract

The current research aims to study the influence of loading Titanium Dioxide (TiO2) nanoparticles on the dielectric, thermal and mechanical properties of the commercial Cross-Linked Polyethylene (XLPE) used as the main insulation in power cables. Using the concept of composite, XLPE/TiO2 nanocomposites samples were prepared by the melt blending method with different ratios of nanoparticles (0.5, 2, 3.5 and 5% wt/wt). The surface treatment of TiO2 nanoparticles was carried out to reduce the agglomeration of TiO2 nanoparticles inside the XLPE. The morphology of the prepared samples was studied by X-ray Diffraction (XRD) and the dispersion of nanoparticles in the XLPE polymer matrix is checked using Field Emission Scanning Electron Microscopy (FE-SEM). Thermal analysis test for all samples have been investigated. The dielectric properties, such as dielectric constant (er) and loss tangent (tan δ) for XLPE/TiO2 nanocomposites were measured under frequencies ranging from 1 Hz to 1 MHz. AC Breakdown Voltage (AC-BDV) was also measured using a controlled high voltage testing transformer (50 Hz) under sphere-to-sphere field. The mechanical properties were evaluated by performing the tensile test and tensile strength and elongation values were measured. It was found that nanocomposites with functionalized TiO2 exhibited better dielectric, thermal and mechanical properties compared to nanocomposites with nonfunctionalized TiO2.

Highlights

  • The excellent characteristics of polymers, such as reliability, availability, low cost, light weight, easy fabrications, and appropriate processing ability, support their using as the main insulation in high voltage cables [1]

  • This study aims to discuss the effect of incorporating nonfunctionalized and functionalized TiO2 with different ratios (0.5, 2, 3.5 and 5% wt/wt) inside the XLPE matrix by an industrial method and show it is an effect on the statistical characteristics of XLPE

  • Field Emission Scanning Electron Microscopy (FE-SEM) Micrographs of XLPE Nanocomposites The surface morphology of the samples was analyzed using FE-SEM which can describe the microstructure dispersion of nanoparticles inside the polymer chains

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Summary

Introduction

The excellent characteristics of polymers, such as reliability, availability, low cost, light weight, easy fabrications, and appropriate processing ability, support their using as the main insulation in high voltage cables [1]. Polyethylene (PE) is the most important polyolefin type because of its superior properties; since it is a semi-crystalline polymer with a low cost and easy to manufacture and fabricate It has a wide array of engineering properties such as toughness, low coefficient of friction, chemical corrosion, and high resistance, and near-zero moisture absorption [2]. All these unique characteristics resulted in an ideal material for many applications especially in electrical insulation. Crosslinked Polyethylene (XLPE) is one shape from PE shapes These polymers are widely used as electrical insulating materials; their high properties can be reduced over time due to different aging processes such as exposure to heat, humidity and mechanical stress [3,4,5].

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