Abstract

A novel AlCrTiSiN high-entropy coating with superior thermal stability and high-temperature oxidation resistance, has been produced. The coating is characterized by unique fcc single-phase solid solution structure with uniform composition, severe lattice distortion and low fcc-AlN solubility, which results in the superior thermal stability. The excellent high-temperature oxidation resistance of coating is attributed to the multi-layer composite structures generated by in-situ reaction of element selective diffusion during the oxidation process. The inner dense SiO2-typed amorphous sub-layer and the intermediate (Al,Cr)2O3-typed sub-layer effectively block the O inward diffusion, and thus enhance the high-temperature oxidation resistance of the coating.

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