Abstract

An efficient H2 pyrolysis method was developed to remove stabilizers on metal surfaces with Ru–poly(amindoamine) as the model. Ru NPs after pyrolysis with the TOF as high as 20 300 h−1 are among the most active solid catalysts for toluene hydrogenation. The high catalytic activity could be mainly attributed to the high exposure degree and accelerating effect of C and N residues at the Ru surface.

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