Enhancing the antifouling and chlorine resistance capabilities of thin-film composite reverse osmosis via surface grafting of dipeptide

Abstract

There has been constant progress in the development of innovative polyamide (PA) thin-film composite (TFC) reverse osmosis (RO) membranes to address limitations in fouling potential, chlorine resistance, salt rejection and water flux trade-offs. In this work, dipeptide of zwitterionic amino acid L-arginine, i.e., arginyl-arginine (Arg-Arg), was grafted on the surface of PA TFC RO membrane in order to simultaneously improve the antifouling properties, chlorine resistance, and separation performance. The interactions between the Arg-Arg dipeptide and PA layer were evidenced by Fourier transforms infrared spectroscopy and nuclear magnetic resonance spectroscopy, which have indicated the distinguished chemical grafting of Arg-Arg dipeptide on the RO membrane surface. The grafting of Arg-Arg dipeptide led to a thinner, smoother, more hydrophilic, and less negatively charged PA surface. The surface-modified membranes simultaneously exhibited enhanced desalination performances, antifouling and chlorine resistance properties. Compared to the neat TFC membrane, the water flux of Arg-Arg dipeptide-modified membrane was improved by 26.19%. The salt rejection also slightly increased from 96.25% to 98%. The roles of Arg-Arg dipeptide in altering the surface chemistry and the structure of the membranes are discussed to highlight the potential of surface-modified membranes in heightening the desalination performances of RO TFC membranes.