Enhancing photocatalytic activity: Investigating the synthesis and characterization of BiVO4/Cu2O/graphene ternary nanocomposites

Abstract

In this study, BiVO4,Cu2O, and grapheneconcentrations have been carefully monitored during the hydrothermalsynthesis of the BiVO4/Cu2O/graphenenanocomposites. The impacts of different concentrations of graphene, time duration and heat treatment temperature have been investigated for synthesized samples. By various characterizations UV–Vis, photoluminescence (PL), FTIR, SEM, XRD and dye degradation, the optical characteristics, vibrational analysis, morphology, structural analysis and photocatalytic activity of the samples examined respectively. The nanocompositeBiVO4/Cu2O with different graphene ratios, the influence on the photocatalytic efficiency and stability of optimal sample has been investigated. BiVO4 and Cu2O concentrations had an impact on the stability of the monoclinic phase of BiVO4, according to X-ray diffraction (XRD) patterns. Nanosheets compositeswith 100 nm average size of nanosheets has observed in SEM micrographs. The e--h+ recombination rate for this sample was lowest according to the PL findings. Also, the optimized sample BiVO4/Cu2O/G5, after 120 min in the visible light spectrum, achieved the greatest degradation of 96% for rhodamine-B (RhB) and 98% for tetracycline (TC) by using optimized photocatalyst BiVO4/Cu2O/G5. Utilizing scavengers, the photocatalytic mechanism has been studied. Recyclability test has been performed to pattern the stability by XRD for optimal sample. To explore the photocatalytic performance, the kinetics of the degradation of RhB and TC have also been examined.