Enhancing barrier properties of cellulose propionate films through the integration of ionic liquid: A study on water pressure resistance

Abstract

This study pioneers the production of porous cellulose propionate (CP) films enhanced with tetrabutylammonium styrenesulfonate ([N4444][SS]), an ionic liquid, to bolster their resistance against water pressure. In contrast to polymer films with ionic liquids that have high moisture permeability, the CP/[N4444][SS] films exhibit remarkable water resistance even under 8 bar pressure. This is due to the physical cross-linking between the [N4444] ions and CP's polar groups, limiting CP chain mobility and thus reducing water interaction. Fourier-transform infrared spectroscopy confirmed these interactions, while scanning electron microscopy revealed a dense, unconnected porous structure. Thermogravimetric and differential scanning calorimetry analyses showed that adding [N4444][SS] increases the CP film's glass transition temperature, indicating enhanced thermal stability. Overall, the study demonstrates that integrating an ionic liquid into CP films significantly improves their barrier capabilities against water and pressure, which has broad implications for various industrial applications.