Abstract
The Bi2Te3, Bi1.9Lu0.1Te3 and Bi1.9Tm0.1Te3 thermoelectrics of n-type conductivity were prepared by microwave-solvothermal method and spark plasma sintering. At the Lu and Tm doping, the Seebeck coefficient increases, while the specific electrical conductivity and total thermal conductivity decreases resulting in thermoelectric efficiency enhancement of Bi2Te3. It is believed that the thermoelectric efficiency can enhance mainly due to formation of narrow impurity Lu or Tm band with high and sharp density of states near the Fermi level. Both increase of the density-of-states effective mass of electrons and decrease of electronic contribution to the total thermal conductivity take place in this case.
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