Abstract
Titanium dioxide (TiO2) has been long used as a photoanode for dye-sensitized solar cells (DSSC) for its high photoreductive capability. One approach towards increasing the performance of TiO2 is to load silver nanoparticles (Ag NP) unto the substrate. In this study, hydrothermal treatment of as-received TiO2 anatase was utilized to fabricate nanostructures that could increase the overall efficiency of DSSC. This hydrothermally-treated TiO2 was loaded with Ag NP via the photodegration of silver nitrate (AgNO3). Characterization of Ag-loaded TiO2 (Ag-TiO2), done using Raman Spectroscopy and Field Emission Scanning Electron Microscopy (FESEM), reveal the anatase characteristic of the samples after hydrothermal treatment, as well as the crystalline structure transformation from tetragonal to monoclinic. Furthermore, upon application of the produced TiO2 samples in DSSC, photovoltaic characteristics were obtained. There was an increase in the current density of all of the Ag-TiO2 samples as compared to the untreated TiO2 sample. The DSSC produced using 0.20 Ag-TiO2 ratio exhibited the highest conversion efficiency, resulting to more than 3000% increase in conversion efficiency from the untreated TiO2 sample.
Published Version
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