Abstract
Structural, dielectric and magnetic properties of dense Dy-substituted strontium titanate ceramics are investigated. In the Sr1-1.5xDyxTiO3 system, incorporation of Dy onto the Sr site is confirmed by a linear decrease of the lattice parameter up to x=0.05. Dielectric spectroscopy analysis of Sr1-1.5xDyxTiO3 ceramics reveals four relaxations. Two relaxations observed below 55K are attributed to dipoles formed by off-centre displacement of Dy3+ ions on the Sr sites. Other two dielectric relaxations found at higher temperatures are attributed to the oxygen vacancy related mechanisms. As result, very high dielectric permittivity of ∼33500 at 28K and of ∼9600 around room temperature at moderate dissipation factor of ∼0.02 are obtained for Sr0.985Dy0.01TiO3 ceramics, making it a promising material for capacitor electronic applications. Paramagnetic behaviour observed for Sr1-1.5xDyxTiO3 as well as for Sr1-xDy2xTi1-xO3 ceramics indicates impossibility to induce a magnetic order and hence magnetoelectric coupling in strontium titanate by Dy substitution.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
