Enhancement of the conjugative electron-releasing power of the hydroxy-group shown by the kinetics of solvolysis of 2-bromo-4-dibromomethylphenol and of 2-bromo-4-dibromomethyl-anisole

Peter B.D De La Mare,Paul A Newman

doi:10.1016/s0040-4039(00)87090-2

Enhancement of the conjugative electron-releasing power of the hydroxy-group shown by the kinetics of solvolysis of 2-bromo-4-dibromomethylphenol and of 2-bromo-4-dibromomethyl-anisole

Peter B.D De La Mare, Paul A Newman

https://doi.org/10.1016/s0040-4039(00)87090-2

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Journal: Tetrahedron Letters	Publication Date: Jan 1, 1982
Citations: 2

Affiliation: University of Auckland

#Relative Rates #Enhancement Of Power + Show 4 more

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Abstract

The relative rates and kinetic forms for the solvolyses of 2-bromo-4-dibromomethyl-phenol and its methyl ether lead to a new estimate (σ + = −1.6) of the electron-releasing power of the hydroxy-group.

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