Enhancement of Pb(ii) adsorptive removal by incorporation of UiO-66-COOH into the magnetic graphitic carbon nitride nanosheets.

Abstract

Efficient elimination of Lead (Pb(ii)) from aqueous solutions has become a crucial area of focus in the wastewater treatment industry. In this study, novel mesoporous magnetic g-C3N4/Fe3O4/UiO-66-COOH was synthesized by combining the acid-functionalized metal-organic framework (MOF) of UiO-66-COOH via a facile novel solvothermal method with magnetic graphitic carbon nitride (g-C3N4/Fe3O4) sheets to enhance Pb(ii) adsorption in water. The study investigated various influential adsorption parameters, including pH, dosage, contact time, ion concentration, and temperature. The Langmuir model, which depicts monolayer adsorption on a uniform surface, was a more suitable fit for the adsorption isotherms. The kinetics conformed to the pseudo-second-order model, indicating a chemical adsorption mechanism. According to the Langmuir model, the adsorption capacity of g-C3N4/Fe3O4/UiO-66-COOH is expected to reach a maximum of 285.8 mg L-1. This value is 2.6 times higher than g-C3N4/Fe3O4 and 1.6 times higher than UiO-66-COOH. The enhanced adsorption capacity of g-C3N4/Fe3O4/UiO-66-COOH is attributed to its superior characteristics, such as abundant functional groups and high surface area which is 2.16 times higher than g-C3N4/Fe3O4. The adsorption thermodynamics indicated that the adsorption occurred spontaneously and was characterized as exothermic. g-C3N4/Fe3O4/UiO-66-COOH material exhibited good recyclability for up to five runs.