Enhancement of NOx adsorption performance on zeolite via a facile modification strategy.

Abstract

Adsorption is a promising technology for simultaneously capturing nitrogen oxides (NOx) from flue gases and recycling NO2 as a profitable chemical, for which a robust and efficient adsorbent provides the key step for success in practical applications. This work reports the enhancement of NOx adsorption performances with less cost of desorption energy on Cu-ZSM-5 zeolites prepared by a facile and rapid (690s) modification method, the incipient-wetness impregnation coupled with microwave drying (IM). In comparisons to H-ZSM-5, Na-ZSM-5 and conventionally liquid-phase ion-exchanged counterparts under sub-1000ppm NOx feed concentrations and room temperature, the IM sample renders a record NOx adsorption capacity (qt,NOx) of 0.878mmol/g from dry gas stream on zeolites, and an applicable qt,NOx of 0.1mmol/g from wet gas stream with a proper copper loading (2.1wt%). The temperature programmed desorption of NOx on the optimal IM sample saturated with NOx from wet gas stream exhibit primary peak temperature lower than reported Cu-ZSM-5 and significant NO2 proportion (72.6%) in desorbed NOx. Deeper insights into advantageous NOx oxidative adsorption over the properly-loaded Cu-ZSM-5 in terms of diverse adsorbate states and competitiveness towards H2O were gained, showing IM method a promising sorbent improvement strategy for practical use.