Abstract

In this work, the ferroelectric characteristic of a 5 nm Hf0.5Zr0.5O2 (HZO) metal-ferroelectric-insulator-semiconductor (MFIS) device is enhanced through strained complementary metal oxide semiconductor (CMOS)-compatible TiN electrode engineering. Strained TiN top-layer electrodes with different nitrogen (N) concentrations are deposited by adjusting the sputtering process conditions. The TiN electrode with 18% N exhibits a compressive characteristic, which induces tensile stress in a 5 nm HZO film. A device with 18% N in TiN shows a higher remanent polarization (2Pr) and larger capacitance value than the compared sample, indicating that the strained TiN is promising for enhancing the ferroelectricity of sub-5 nm HZO devices.

Highlights

  • Technologies by Using a Strained TiNHfO2 -based dielectrics are promising ferroelectric materials for nonvolatile memory, negative-capacitance FETs, and neuromorphic applications because of their compatibility with complementary metal-oxide-semiconductor (CMOS) technology [1,2]

  • To further enhance the performance in ferroelectric FETs (FeFETs) and negative-capacitance FETs (NCFETs), it is important to enhance the ferroelectricity in metal-ferroelectric-insulator-semiconductor (MFIS) devices, which is the major foundation for high-performance FeFETs and NCFETs

  • Is relatively thin compared with the bottom electrode and top electrode, the reporting literature only consider the coefficient of thermal expansion (CTE) between the bottom electrode and top electrode [6]

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Summary

Introduction

HfO2 -based dielectrics are promising ferroelectric materials for nonvolatile memory, negative-capacitance FETs, and neuromorphic applications because of their compatibility with complementary metal-oxide-semiconductor (CMOS) technology [1,2]. Studies have reported that the strain exerted through the different electrodes and substrates [4,5,6,7] can be used as an alternative method of inducing the ferroelectric characteristic because the tensile stress along the in-plane direction can enhance transformation from the tetragonal phase to the orthorhombic phase. To further enhance the performance in ferroelectric FETs (FeFETs) and negative-capacitance FETs (NCFETs), it is important to enhance the ferroelectricity in metal-ferroelectric-insulator-semiconductor (MFIS) devices, which is the major foundation for high-performance FeFETs and NCFETs. in this study, we report, to the best of our knowledge for the first time, using strained TiN as a top electrode in 5 nm

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