Enhancement of critical current density using micro-porous structure in a low-temperature water electrolysis

Abstract

The critical current density (CCD), which limits the hydrogen production rate was measured by forming micro-porous structures on the cathode electrode in a low-temperature water electrolysis. Several micro-porous structures were formed by the electrodeposition method varying the current density during the deposition. A maximum 54% enhancement of the CCD was recorded compared to the plain surface. With the micro-porous structures, the superior capillary wicking effect allowed the electrolyte to penetrate the structure, resulting in the increased number of hydrogen nucleation sites. The increased hydrogen nucleation sites led to the decreased hydrogen bubble size and increased departed bubble density, which delayed formation of the hydrogen film leading to the CCD. The surface morphology revealed that the multiple pore layers with the interconnected pores exhibited superior capillary wicking effect compared to the open type single pore layer. It is expected that the results of present work stimulate further research regarding electrode surface design in the low-temperature water electrolysis.