Enhancement of Cd‐Free All‐Dry‐Processed Cu(In1‐x,Gax)Se2 Thin‐Film Solar Cells by Simultaneous Adoption of an Enlarged Bandgap Absorber and Tunable Bandgap Zn1‐xMgxO Buffer

Abstract

Attempts to remove environmentally harmful materials in mass production industries are always a major issue and draw attention if the substitution guarantees a chance to lower fabrication cost and to improve device performance, as in a wide bandgap Zn1‐xMgxO (ZMO) to replace the CdS buffer in Cu(In1‐x,Gax)Se2 (CIGSe) thin‐film solar cell structure. ZMO is one of the candidates for the buffer material in CIGSe thin‐film solar cells with a wide and controllable bandgap depending on the Mg content, which can be helpful in attaining a suitable conduction band offset. Hence, compared to the fixed and limited bandgap of a CdS buffer, a ZMO buffer may provide advantages in Voc and Jsc based on its controllable and wide bandgap, even with a relatively wider bandgap CIGSe thin‐film solar cell. In addition, to solve problems with the defect sites at the ZMO/CIGSe junction interface, a few‐nanometer ZnS layer is employed for heterojunction interface passivation, forming a ZMO/ZnS buffer structure by atomic layer deposition (ALD). Finally, a Cd‐free all‐dry‐processed CIGSe solar cell with a wider bandgap (1.25 eV) and ALD‐grown buffer structure exhibited the best power conversion efficiency of 19.1%, which exhibited a higher performance than the CdS counterpart.